1 华南师范大学光子中医学实验室, 广东 广州 510631
2 赣南师范学院物理与电子信息学院, 江西 赣州 341000
采用拉曼光谱作为分析手段,以近红外激光785 nm波长激发,获得了真、假一百元人民币在固定人像水印、全息开窗安全线、隐形面额数字和光变油墨数字等处的谱图。发现真币与假币的谱图有明显差别,而且不同来源的假币的拉曼光谱也存在着可分辨的差异。研究表明,利用拉曼光谱的分子指纹和微区分析能力,不仅对伪造、变造人民币的识别有重要价值,而且可以分辨不同来源的假币。
光谱学 光谱分析 假币鉴别 拉曼光谱 近红外激光
Author Affiliations
Abstract
Photonic Chinese Medicine Lab, South China Normal University, Guangzhou 5106312School of Physics and Electronic Information Science, Gannan Teachers College, Ganzhou 3410003Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510631
A·C mismatches are studied by Raman spectral characterization of PolyA, PolyC, and their equimolar complex in solution of 0.14 mol/L Na+, pH7.0. Experimental results show that A·C mismatches occur to be A/B (mainly A) conformers, and unlike Watson-Crick base pairing, this kind of mismatches is stabilized by only one hydrogen bond involving cytosine N4H2 and adenine N7. The formation of A·C complex makes the base stacking interactions much stronger, and conformation of the backbone more ordered, which leads to obvious Raman hypochromic effect with some shifts in corresponding bands.
A·C碱基错配对 喇曼光谱 多聚腺嘌呤核苷酸 多聚胞嘧啶核苷酸 170.5660 Raman spectroscopy 300.6170 Spectra 300.6330 Spectroscopy, inelastic scattering including Raman 300.6450 Spectroscopy, Raman 300.6390 Spectroscopy, molecular Chinese Optics Letters
2008, 6(1): 0161
